Throwing some light on blackwater...

It goes without saying that the single most important component of our aquariums is also the most obvious...water! As the literal bearer of life and the environment in which our fishes, plants, and other organisms thrive, it's fundamental. it's the reason we're drawn to fishes, not gerbils, Tarantula, or Mice- or whatever other pets people keep!

Yeah, we're into water!

And I dear say that we take it for granted a bit.

Now, sure, some hobbyist rightfully place the importance of good quality, properly-conditioned water at the very top of their "want list" of "Stuff" required for successful aquariums. These are often fish breeders and very serious hobbyists, who understand the fundamental importance of good water for their work.

Some of the most common questions we receive lately are "How much _______ do I need to get my water to look like________?" or "How much_______ is needed to lower the pH in my tank?" Or, "How much do I need to get a good amount of humic substances and tannins into my aquarium?"

I usually respond with a simple, "I don't know."

These are all really good questions. Logical. Important.  I kind of feel like many hobbyists are looking for a plug-and-play "formula" or "recipe" for how to accomplish certain water-conditioning tasks.

I totally get that. But the reality is...there IS no "recipe" for how to do this stuff.

And it sucks, I know.

"Why, Scott? I read that you can just add some of this blackwater extract that you can buy online, and maybe add some catappa leaves, and..."

Stop. STOP. Please, we're just making this painful.

Simply adding leaves or bottled extracts to your tap water isn't going to result in "Instant Amazon" or whatever. There are numerous complexities and nuances which contribute to these habitats that to simply recommend adding "X" to your water isn't the whole story.

There are so many variables in the equation that it's almost impossible to give a definitive answer. And yeah, us guys in the botanical biz haven't really helped the situation. Over the years, vendors who sold catappa leaves, for example, would recommend starting amounts ("three leaves per 15 liters of water" or whatever...) of botanical materials to use in aquariums.

I mean, we've sort of done it, too...And, although our recommended "dosage" of leaves was given for different reasons (to avoid adding too much material to your tank too quickly), the idea of a "recipe" in general is kind of delusional, IMHO.

Now, this was all well and good, but it's based on....what? I mean, is this based on how many leaves of _______ size that a typical hobbyist with a 10-gallon aquarium needs to get the water "looking brown?" Or to lower tap water with a starting pH of 7.4 and a KH of ___ to pH of 6.9? Or to impart "x" ppm of tannins or humic substances into this given quantity of water?

See? Add to this story the fact that you really can't soften water and make it more "malleable" by using botanicals or extracts alone, and you've got a good case for confusion! It's just not that simple.

Maybe we can gain a bit of understanding- or at least, an appreciation for the dynamics of this process, by looking once again to Nature.

Have you very thought about how water reaches all of the wild aquatic systems of the world? I mean, it's got to get there some way, right? So, how does it reach the ponds, lakes, streams, and rivers and forest floors of the world?

Well, some simply falls into the body of water directly from the sky, and that's that. Some is a result of other overflowing streams and rivers (like, ya' know- those flooded Igapo forests we talk about!). Inputs of precipitation falling over the area of an aquatic habitat are transferred to the habitat via a number of different pathways.

It's surprisingly complicated.

There's like a whole field of science devoted to studying this process! It's called Hydrology, and it's incredibly interesting...As fish geeks, we're probably already acquainted with this field of study, at least tangentially! 

So, water comes from a variety of sources, reaching a myriad of ecological niches. However, not all of the water has such an easy journey on its way into our favorite aquatic habitat!

Even in the case of rainwater, some of it simply lands on tree leaves in the surrounding area and evaporates. This is a process scientists call "interception", and accounts for the fact that not all water makes it to the ground. Water that does reach the ground enters the soil through a process called infiltration. slowly percolating down to soil areas known as the "saturated zone"- and as you'd imagine, this is where the fun really begins! (to a soil geologist, at least!)

The soil properties control the infiltration capacity; these include things like soil permeability, the presence of vegetation and plant roots, and how much water is already in the soil. Through what is known as "ground water flow", ultimately, the water finds it way into our favorite aquatic habitats. It's important to note that soil texture ( the relative proportion of sand, silt and clay particles within the mix) affects infiltration rates. 

Sandy soils like the "podzols", common to forested areas of South America that we've talked about have higher permeability than some clay-based soils. In some really arid areas a "crust" can form on the soil surface, decreasing the permeability. And of course, the thickness of the soil directly affects how much water the soil can actually absorb.

And, in many cases, the substrate composition and its relationship with water has direct impact on the life forms which inhabit these aquatic systems. In the case of some habitats, like vernal pools, which are filled with water seasonally, the substrate is of critical importance to the aquatic life forms which reside there.

Yeah, soils and geology are perhaps the primary driver of water composition in Nature. 

Let's talk more about "blackwater."

In a blackwater environment, the color is a visual indicator of an influx of dissolved materials that contribute to the "richness" of the environment. Indeed, a blackwater environment is typically described as an aquatic system in which vegetation decays, creating  tannins that leach into the water, making a transparent, acidic water that is darkly stained, resembling tea.

But, that's not the whole story, really.

It’s important to really try to understand the most simple of questions- like, what exactly is “blackwater”, anyways?

A scientist or ecologist will tell you that blackwater is created by draining from older rocks and soils (in Amazonia, look up the “Guyana Shield”), which result in dissolved fulvic and humic substances, present small amounts of suspended sediment, and characterized by lower pH (4.0 to 6.0) and dissolved elements, yet higher SiO₂ contents. Magnesium, Sodium, Potassium, and Calcium concentrations are typically very low in blackwater. Electrical conductivity (ORP) is also lower than in so-called "whitewater" habitats.

Tannins are also imparted into the water by leaves and other botanical materials which accumulate in these habitats.

 

The action of water upon fallen leaves and other botanical-derived materials leaches various compounds out of them, creating the deep tint that many of us are so familiar with. Indeed, this "leaching" process is analogous to boiling leaves for tea. The leached compounds are both organic and inorganic, and include things like tannin, carbohydrates, organic acids, pectic compounds, minerals, growth hormones, alkaloids, and phenolic compounds.

Most of the of the extractable substances in the surface litter layer are humic acids, typically coming from decaying plant material. Scientists have concluded that greater input of plant litter leads to greater input of humic substances into ground water.

In other words, those leaves that accumulate on the substrate are putting out significant amounts of humic acids, as we've talked about previously! And although humic substances, like fulvic acid, are found in both blackwater and clear water habitats, the organic detritus (you know, from leaves and such) in blackwater contains more extractable fulvic acid than in clearwater  habitats, as one might suspect!

The Rio Negro, for example, contains mostly humic acids, indicating that suspended sediment selectively adsorbs humic acids from black water.  The low concentration of suspended sediments in rivers like the Rio Negro is one of the main reasons why high concentrations of humic acids are maintained. With little to no suspended sediment, there is no "adsorbent surface" (other than the substrate of the river, upon which these acids can be taken hold of (adsorb).

When you think about it, all of this this kind of contributes to why blackwater has the color that it does, too. Blackwater in the Amazon basin is colored reddish-brown. Why? Well, it has  those organic compounds dissolved in it, of course. And most light absorbtion is in the blue region of the spectrum, and the water is almost transparent to red light, which explains the red coloration of the water!

And many of those organic compounds come from the surrounding land, as touched on above...

In summary, natural "blackwaters" typically arise from highly leached (tropical) environments where most of the soluble elements in the surrounding rocks and soils are rapidly removed by heavy rainfall. Materials such as soils are the primary influence on the composition of blackwater.

Leaves and other materials contribute to the process and appearance in Nature, but are NOT the primary “drivers” of its creation and composition.

 

So, right from the start, it’s evident that natural blackwater is “all about the soils…” Yeah, I'll repeat it again: It’s more a product of geology than just about anything else. 

More confusing, recent studies have found that most of the acidity in black waters can be attributed to dissolved organic substances, and not to dissolved carbonic acid. In other words, organic acids from compounds found in soil and decomposing plant material, as opposed to inorganic sources. Blackwaters are almost always characterized by high percentages of organic acids.

Despite the appearance, as a general rule, blackwater rivers are lower in nutrients than clear rivers. Wouldn't it be interesting, when contemplating more natural biotope/biotype aquariums, to study and take into consideration the surrounding geology and physical characteristics of the habitat?  Too recreate the habitat based on the soil or geological composition of the surrounding terrestrial environment?

As we know now, the influence of factors like soil, and the presence of terrestrial materials like seed pods, leaves, and branches play a huge role in the chemical composition and appearance-of the water. It's really no different in the aquarium, right?

Like so many things in nature, the complexity of blackwater habitats is more than what meets the eye. Chemically, biologically, and ecologically, blackwater habitats are a weave of interdependencies- with soil, water, and surrounding forest all functioning together to influence the lives of the fishes which reside within them. No single factor could provide all of the necessary components for fish populations to thrive.

To damage or destroy any one of them could spell disaster for the fishes- and the ecosystem which supports them. It is therefore incumbent upon us to understand, protect, and cherish these precious habitats, for the benefit of future generations. 

And with regards to our aquarium work?

Although there may even be breakthroughs in terms of blackwater extracts and additives coming to market, there are still a lot of questions that would have to be answered before we could simply state that "X" drops per gallon of such an such a formula would yield a specific outcome. This reminds me of the reef aquarium world more an more, lol.

So, if I've made any "argument" here, it's that this stuff is every bit as much of an "art"- in terms of aquarium keeping- as it is a "science." We will, at least for the foreseeable future, have to use the data we have available and formulate a best guess as to how much of what can give us some of the impacts we are interested in for our aquariums.

We simply can't authoritatively make blanket statements like, "You need to use "X" catappa leaves per gallon in order to recreate Rio Negro-like conditions in your aquarium!" We can't simply state that you can throw in some podzolic soil and achieve blackwater, either. There are many factors in play, as we've discussed here, right?

Marketing hyperbole aside, we really are sort of...guessing.

And that's certainly nothing to be discouraged about!

We, as a community, are getting deeper into the functional aspects of blackwater, botanical-style aquariums than ever before. More light is being shed on what's going on in both our aquariums and in the natural habitats we desire to replicate. We are learning more every day about how the presence of tannins and humic substances in our aquariums is affecting the health, longevity, and spawning behaviors of our blackwater fishes.

We're learning about the challenges and realities of managing blackwater systems over the long term- understanding the good, the bad, and the dangerous possibilities that are present when we experiment with these ideas.

There is much, much more work to be done..And a lot of talented hobbyists like yourself are out there on the front lines every day, contributing to the body of knowledge that will benefit the hobby for generations!

Stay persistent. Stay bold. Stay open-minded. Stay curious. Stay disciplined...

And Stay Wet.

 

Scott Fellman

Tannin Aquatics 

 

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